Studies on color reaction of hydrazides with ninhydrin

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Cyanide reaction with ninhydrin: elucidation of reaction and interference mechanisms.

A new sensitive spectrophotometric method has recently been developed for the trace determination of cyanide with ninhydrin. Cyanide ion was supposed to act as a specific base catalyst. Nevertheless, this paper demonstrates that the reported assay is based on a novel reaction of cyanide with 2,2-dihydroxy-1,3-indanedione, which affords purple or blue colored salts of 2-cyano-1,2,3-trihydroxy-2H...

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The Ninhydrin Reaction with Amines and Amides

1 Harding, V. J., and Warneford, F. H. S., J. Biol. Chem., 1916, xxv, 319. 2 Dakin, H. D., and Dudley, H. W., J. Biol. Chem., 1913, xv, 127. 3 Neuberg, C., Biochem. Z., 1913, lvi, 500. 4 Ruhemann, S., J. Chem. Sot. 1910, xcvii, 2026. 5 In this and the preceding paper triketohydrindene hydrate has sometimes been written as the triketone for the sake of simplicity in explaining the decompositions...

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The ninhydrin reaction and its analytical applications.

Feuge, R. O., Cousins, E. R., Fore, S. P., Dupre, E. F. & O'Connor, R. T. (1953). J. Amer. Oil Chem. Soc. 30, 454. Feuge, R. O., Pepper, M. B. jun., O'Connor, R. T. & Field, E. T. (1951). J. Amer. Oil Chem. Soc. 28, 420. Garton, G. A. (1954). J. Sci. Fd Agric. 5, 251. Grass Driers' Association (1941). Analyst, 66, 334. Hartman, L., Shorland, F. B. & McDonald, I. R. C. (1954). Nature, Lond., 174...

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The Ninhydrin Reaction with Amines and Amides. by Victor

1 Harding, V. J., and Warneford, F. H. S., J. Biol. Chem., 1916, xxv, 319. 2 Dakin, H. D., and Dudley, H. W., J. Biol. Chem., 1913, xv, 127. 3 Neuberg, C., Biochem. Z., 1913, lvi, 500. 4 Ruhemann, S., J. Chem. Sot. 1910, xcvii, 2026. 5 In this and the preceding paper triketohydrindene hydrate has sometimes been written as the triketone for the sake of simplicity in explaining the decompositions...

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ON THE MECHANISM OF THE REACTION OF NINHYDRIN WITH a-AMINO ACIDS

Our purpose is to show by means of a quantitative method for determination of hydrindantin derivatives that previous concepts of the mechanism of the reaction of ninhydrin with amino acids are inadequate or erroneous, and to show facts supporting a new concept. The main facts are as follows: (a) Hydrindantin forms when amino acids react with ninhydrin (Ruhemann (1) ; Abderhalden (2)) ; (b) it r...

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ژورنال

عنوان ژورنال: BUNSEKI KAGAKU

سال: 1962

ISSN: 0525-1931

DOI: 10.2116/bunsekikagaku.11.1255